LDPE is defined by a density range of 917–930 kg/m3.[6] At room temperature it is not reactive, except to strong oxidizers; some solvents cause it to swell. It can withstand temperatures of 65 °C (149 °F) continuously[6] and 90 °C (194 °F) for a short time. Made in translucent and opaque variations, it is quite flexible and tough.
LDPE has more branching (on about 2% of the carbon atoms) than HDPE, so its intermolecular forces (instantaneous-dipole induced-dipole attraction) are weaker, its tensile strength is lower, and its resilience is higher. The side branches mean that its molecules are less tightly packed and less crystalline, and therefore its density is lower.
When exposed to consistent sunlight, the plastic produces significant amounts of two greenhouse gases: methane and ethylene. Because of its lower density (high branching), it breaks down more easily than other plastics; as this happens, the surface area increases. Production of these trace gases from virgin plastics increases with surface area and with time, so that LDPE emits greenhouse gases at a more unsustainable rate than other plastics. In a test at the end of 212 days' incubation, emissions recorded were 5.8 nmol g-1 d-1 of methane, 14.5 nmol g−1 d−1 of ethylene, 3.9 nmol g−1 d−1 of ethane, and 9.7 nmol g−1 d−1 of propylene. When incubated in air, LDPE emits methane and ethylene at rates about 2 times and about 76 times, respectively, more than in water.[7]
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